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CFCs

Chlorofluorocarbons (CFCs) are a family of chemical compounds developed back in the 1930's as safe, non-toxic, non-flammable alternative to dangerous substances like ammonia for purposes of refrigeration and spray can propellants. Their usage grew enormously over the years. One of the elements that make up CFCs is chlorine. Very little chlorine exists naturally in the atmosphere. But it turns out that CFCs are an excellent way of introducing chlorine into the ozone layer. The ultraviolet radiation at this altitude breaks down CFCs, freeing the chlorine. Under the proper conditions, this chlorine has the potential to destroy large amounts of ozone. This has indeed been observed, especially over Antarctica. As a consequence, levels of genetically harmful ultraviolet radiation have increased.

Chlorofluorocarbons (CFCs) are highly stable compounds that are used as propellents in spray cans and in refrigeration units. They are several organic compounds composed of carbon, fluorine, chlorine, and hydrogen. CFCs are manufactured under the trade name Freon (q.v.). 

Developed during the 1930s, CFCs found wide application after World War II. These halogenated hydrocarbons, notably trichlorofluoromethane (CFC-11, or F-11) and dichlorodifluoromethane (CFC-12, or F-12), have been used extensively as aerosol-spray propellants, refrigerants, solvents, and foam-blowing agents. They are well-suited for these and other applications because they are nontoxic and nonflammable and can be readily converted from a liquid to a gas and vice versa.

Chlorofluorocarbons or CFCs (also known as Freon) are non-toxic, non-flammable and non-carcinogenic. They contain fluorine atoms, carbon atoms and chlorine atoms. The 5 main CFCs include CFC-11 (trichlorofluoromethane - CFCl3), CFC-12 (dichloro-difluoromethane - CF2Cl2), CFC-113 (trichloro-trifluoroethane - C2F3Cl3), CFC-114 (dichloro-tetrfluoroethane - C2F4Cl2), and CFC-115 (chloropentafluoroethane - C2F5Cl).

CFCs have been found to pose a serious environmental threat. Studies undertaken by various scientists during the 1970s revealed that CFCs released into the atmosphere accumulate in the stratosphere, where they had a deleterious effect on the ozone layer. Stratospheric ozone shields living organisms on Earth from the harmful effects of the Sun's ultraviolet radiation; even a relatively small decrease in the stratospheric ozone concentration can result in an increased incidence of skin cancer in humans and in genetic damage in many organisms. In the stratosphere the CFC molecules break down by the action of solar ultraviolet radiation and release their constituent chlorine atoms. These then react with the ozone molecules, resulting in their removal.

CFCs have a lifetime in the atmosphere of about 20 to 100 years, and consequently one free chlorine atom from a CFC molecule can do a lot of damage, destroying ozone molecules for a long time. Although emissions of CFCs around the developed world have largely ceased due to international control agreements, the damage to the stratospheric ozone layer will continue well into the 21st century.

Source: http://www.theozonehole.com/ozone.htm